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Deep soil samples (also known as profile soil samples) were taken from depths of between 35 cm and 50 cm at densities of 1 sample per two square kilometres (rural / regional areas) and 4 samples per square kilometre (urban areas). The G-BASE profile soils were generally sieved to 150 microns before analysis and determined by XRF for some or all of: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Since 2003, for both regional and urban sampling, deep soil samples and shallow soil samples were routinely collected from the same sites, but only the shallow soil samples were submitted for chemical analysis. The deep soil samples were archived in the National Geoscience Data Centre. 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The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. The routine collection of regional soil samples was introduced in 1986 in areas of poor drainage density, with an average sample density of one site per 2 square kilometres. Urban soil sampling commenced in 1991, with an average density of four samples per square kilometres, for the urban areas of Belfast, Cardiff, Corby, Coventry, Derby, Doncaster, Glasgow, Hull, Ipswich, Leicester, Lincoln, Manchester, Mansfield, Northampton, Nottingham, Peterborough, Scunthorpe, Sheffield, Swansea, Stoke, Telford, Wolverhampton and York. Topsoil samples were collected between depths of 5 cm and 20 cm, and were sieved through a 2 mm mesh and milled to less than 150 microns. The data include XRF and direct-reading optical emission spectrometry (DR-OES) analyses for some or all of the following elements: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Loss on Ignition (LOI) and pH (in a slurry of 0.01 M CaCl2) were also routinely determined on 50% of regional and all urban samples. 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The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. Stream sediments were the primary sample medium for G-BASE, with an average density of one site per 1.5 km square. The drainage sampling sites cover most of Great Britain. Sediment was collected from the centre of the stream and sieved through two sieves (2 mm and 150 µm) to obtain a fine grain-size fraction of <150 microns. Analytical data (by a variety of analytical methods, including XRF and direct-reading optical emission spectrometry (DR-OES) for the <150 micron fraction of stream sediment samples are available for some or all of the following elements: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Some stream sediment samples were originally collected as part of the Mineral Reconnaissance Programme (MRP), and later re-analysed for G-BASE. These samples may have been assigned a new sample number, but will plot at the same site. 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